Co–Gd phosphonate complexes as magnetic refrigerants
نویسندگان
چکیده
منابع مشابه
HFC & HC Blends as Refrigerants
The blends formed mixing hydrofluorocarbons (HFC) and hydrocarbons (HC) can be classified as semi-natural refrigerants since, by optimizing the composition, it is in principle possible to adapt basic features such as GWP, TEWI and flammability to the industrial and environmental requirements. However, the energetic efficiency must be competitive with the traditional refrigerants. To evaluate th...
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Ligands with geminal bis(phosphonic acid) appended to 1,4,7-triazacyclonone-1,4-diacetic acid fragment through acetamide (NOTAM(BP) ) or methylenephosphinate (NO2AP(BP) ) spacers designed for (68) Ga were prepared. Ga(III) complexation is much faster for ligand with methylenephosphinate spacer than that with acetamide one, in both chemical (high reactant concentrations) and radiolabeling studie...
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31P NMR spectra of phosphate and phosphonate complexes of Escherichia coli alkaline phosphatase have been obtained by Fourier transform NMR methods. One equivalent of P1i, bound to Zn(II) alkaline phosphatase, pH 8, gives rise to a single 31P resonance 2 ppm downfield from that for Pi, and assignable to the noncovalent complex, E-P. Inorganic phosphate in excess of 1 eq per enzyme dimer gives r...
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ژورنال
عنوان ژورنال: Chem. Sci.
سال: 2011
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c0sc00371a